Sodium ion Battery 101

Explore the essentials of Sodium ion (Na ion) batteries with our comprehensive guide, breaking down the key aspects of this innovative energy solution.

We’re here to help you understand the basics of Sodium ion(Na ion) battery. We will delve into the fascinating world of sodium ion (Na ion) batteries, an emerging technology that is shaping the future of energy storage. As the demand for sustainable and efficient energy solutions grows, understanding the mechanics, advantages, and potential applications of sodium ion batteries becomes increasingly important.

Whether you are a technology enthusiast, a sustainability advocate, or simply curious about the latest advancements in battery technology, this guide will provide you with a comprehensive overview of sodium ion batteries, from their basic principles to their role in revolutionizing energy storage and usage. So, let’s embark on this enlightening journey into the realm of sodium ion batteries, exploring what makes them a promising alternative in the world of renewable energy.

What is Sodium ion Battery(Na ion Battery)?

Sodium-ion battery (SIBs, NIBs, or Na ion battery) is a type of rechargeable battery that primarily relies on the movement of sodium ions between the cathode and anode for its operation, similar to the working principle of lithium-ion batteries. During charging, sodium ions (Na+) ions are deintercalated from the cathode and move to the anode; during discharging, Na+ ions return to the cathode from the anode, and electrons in the external circuit move from the anode to the cathode, reducing Na+ back to Na. Like lithium-ion batteries, sodium-ion batteries are also a type of rechargeable secondary battery.

Datasheet of the CATL first-generation sodium-ion battery performance
(Image credit: CnEVPost)

Sodium-ion batteries offer superior safety, discharge characteristics, and operating temperature range. A sodium battery can discharge down to 0 volts without facing the safety issues that lithium batteries encounter under the same condition; a sodium salt electrolyte solution has a higher ionic conductivity than a lithium salt electrolyte solution of the same concentration, which accounts for the superior fast-charging performance of sodium-ion batteries; sodium-ion batteries also perform better at low temperatures, maintaining over 88% discharge retention even in environments as cold as -20°C.

Advantages of the first-generation sodium-ion battery performance
Advantages of the first-generation sodium-ion battery performance

Sodium-ion batteries (SIBs) are emerging as an alternative to lithium-ion batteries, currently dominating the rechargeable battery market for electric vehicles and energy storage systems (ESS).

Learn more>>> What is Sodium ion Battery Cell? LiFePO4 Alternative?

Common Sodium ion Battery Shapes

The selection of sodium battery forms should be adapted based on the needs of the end application, thereby leveraging the advantages of different battery shapes in structure, process, and equipment maturity.

Cylindrical
HIGHSTAR_NaCR18650-1.3ER Na-ion Cylindrical Cell
Prismatic
HIGHSTAR_NaCP50160118-70E3 Na-ion Prismatic Cell
Pouch
LiFun Na-ion Pouch Cell

Cylindrical Sodium Battery

The cylindrical sodium battery is a common type of battery with a cylindrical shape. It consists of a cathode, an anode, and an electrolyte. The cathode material is usually an oxide, while the anode is made of metallic sodium. The electrolyte is a conductive liquid or solid that can conduct ions within the battery. Cylindrical sodium batteries have high energy density and a long lifespan, making them widely used in portable power sources, electric vehicles, and other areas. Additionally, they have high safety performance and can operate stably at high temperatures.

Prismatic Sodium Battery

Prismatic sodium batteries, another common type, have a square or rectangular shape. Compared to cylindrical batteries, they are more compact in shape, making better use of space. The structure of prismatic sodium batteries is similar to that of cylindrical ones, consisting of a cathode, an anode, and an electrolyte. These batteries are used in a wide range of applications, including electronic products, household appliances, and industrial equipment. Prismatic sodium batteries have high energy density and a long lifespan, meeting the needs of various fields.

Pouch Sodium Battery

Pouch sodium batteries are a relatively new type of battery, characterized by their soft packaging. Compared to cylindrical and prismatic batteries, they are more flexible in shape and can be designed and manufactured according to specific needs. Pouch sodium batteries have a relatively simple structure, composed of stacked layers of cathode, anode, and electrolyte. They offer high energy density, lighter weight, and smaller volume, making them widely used in mobile devices, drones, and other areas. Moreover, pouch sodium batteries have good safety performance, effectively preventing issues like short-circuiting and overcharging.

Cylindrical, prismatic, and pouch sodium batteries are three common types of batteries, each differing in shape, structure, and application fields. Cylindrical and prismatic sodium batteries, with their high energy density and long lifespan, are extensively used in portable power sources and electric vehicles. Pouch sodium batteries, characterized by their high energy density, light weight, and small volume, are suitable for mobile devices and drones. Regardless of the type, it is crucial to strictly control the usage environment and charging/discharging conditions of sodium batteries to ensure their safety and lifespan.

Sodium ion Battery Charging and Discharging Principle

Sodium-ion batteries operate on the same principle as lithium-ion batteries. This involves the intercalation/deintercalation and insertion/extraction of lithium ions between the anode and cathode during charging and discharging processes, which is why they are also referred to as “rocking chair batteries.” Lithium-ion batteries primarily work by the movement of lithium ions between the cathode and anode, using intercalated lithium compounds as cathode material. Sodium-ion batteries work as follows: during charging, Na+ ions are de-intercalated from the cathode and intercalated into the anode through the electrolyte; during discharging, the process is reversed.

(Image credit: HiNa Battery Technology Co., Ltd)

Sodium ion Battery Vs. Other Batteries

(NIBs vs. LIBs vs. Lead-Acid Batteries | Image credit: HiNa Battery Technology Co., Ltd)

What’s the Difference Between Sodium ion and LiFePO4 Batteries?

In order to provide a clear and concise comparison between Sodium-ion and LiFePO4 battery cells, we have compiled a comprehensive chart that highlights the critical differences in their specifications and performance characteristics. This chart serves as a valuable reference for anyone looking to understand the nuances between these two types of battery technologies, which are both pivotal in the realm of energy storage solutions. By examining the various attributes outlined in the chart, users can gain insights into which battery cell type best suits their specific needs and applications. Let’s delve into the detailed comparison presented in the “Sodium-ion vs. LiFePO4 Battery Cell Chart.”

For an in-depth analysis of the advantages, disadvantages, and key differences between Sodium-ion and LiFePO4 batteries, check: Sodium-ion VS LiFePO4 Battery Compared: Pros, Cons, and Differences

Key Sodium ion Battery Manufacturers

A list of major Sodium-ion battery manufacturers, where you can learn about each manufacturer’s info and leading na-ion battery solutions.

Learn more: List of Main Sodium ion Battery Manufacturers [2024]